572914-98-8

Basic information

• Product Name: [(C₅Me₅)IrCl₂(bis(diphenylphosphinomethyl)phenylphosphine)IrCl(C₅Me₅)]PF₆
• CAS NO: 572914-98-8
• Molecular Weight: 1412.72
• Mol File: 572914-98-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(C₅Me₅)IrCl₂(bis(diphenylphosphinomethyl)phenylphosphine)IrCl(C₅Me₅)]PF₆(CAS DataBase Reference)
• NIST Chemistry Reference: [(C₅Me₅)IrCl₂(bis(diphenylphosphinomethyl)phenylphosphine)IrCl(C₅Me₅)]PF₆(572914-98-8)
• EPA Substance Registry System: [(C₅Me₅)IrCl₂(bis(diphenylphosphinomethyl)phenylphosphine)IrCl(C₅Me₅)]PF₆(572914-98-8)

Safety Data

• Hazardous Substances Data: 572914-98-8(Hazardous Substances Data)

Upstream product

• 17084-13-8 potassium hexafluorophosphate 
• 12354-84-6 bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] 
• 2071-24-1 bis(diphenylphosphinomethyl)phenylphosphine 
• 572914-98-8 [(C₅Me₅)IrCl₂(bis(diphenylphosphinomethyl)phenylphosphine)IrCl(C₅Me₅)]PF₆ 

Downstream Products

• 572914-98-8 [(C₅Me₅)IrCl₂(bis(diphenylphosphinomethyl)phenylphosphine)IrCl(C₅Me₅)]PF₆ 

Relevant articles and documents

Stereochemistry of mono- and dinuclear complexes of rhodium, iridium and ruthenium bearing bis(diphenylphosphinomethyl)phenylphosphine

Reaction of [Cp*MCl2]2 (1a: M=Rh and 1b: M=Ir) or [(C6Me6)RuCl2]2 (1c) with bis(diphenylphosphinomethyl)phenylphosphine (dpmp) in the presence of KPF6 generated mono- or dinuclear complexes [Cp*RhCl(dpmp)](PF6) (2a), [(C6Me6) RuCl(dpmp)](PF6) (5c), [Cp*MCl2(dpmp)MClCp*] (PF6) (3a: M=Rh and 4b: M=Ir) or [(C6Me6)RuCl2 (dpmp)RuCl(C6Me6)](PF6) (6c), depending on reaction conditions. These complexes have two chiral centers and the diastereomers were separated and characterized by spectrometry and X-ray analyses. A diastereomer 2a(A) was treated with AuCl(C4H8S), generating a hetero-tetranuclear complex [{Cp*RhCl2(dpmp)Au}2] (PF6)2 (7a), whereas similar reactions of 5c gave dinuclear complex [(C6Me6)RuCl(dpmp)AuCl] (PF6) (8c(A)).