57355-72-3Relevant academic research and scientific papers
Photochemical synthesis of 3-alkynals from 1-alkynoxy-9,10-anthraquinones
Blankespoor, Ronald L.,Boldenow, Peter J.,Hansen, Eric C.,Kallemeyn, Jeffrey M.,Lohse, Andrew G.,Rubush, David M.,Vrieze, Derek
, p. 3933 - 3935 (2009)
(Chemical Equation Presented) Photolysis of 1-(3-alkynoxy)-9,10- anthraquinones in deoxygenated methanol leads to moderate yields (35-45%) of 3-alkynals along with the unexpected formation of diacetals. Reaction of these 3-alkynals with Grignard and Witti
TMSBr/InBr3-promoted Prins cyclization/homobromination of dienyl alcohol with aldehyde to construct cis-THP containing an exocyclic E-alkene
Li, Linjie,Sun, Xianwei,He, Yanyang,Gao, Lu,Song, Zhenlei
, p. 14925 - 14928 (2015)
A TMSBr/InBr3-promoted Prins cyclization/homobromination reaction of dienyl alcohol with aldehyde has been developed to construct a unique cis-E THP shown as the A ring in (-)-exiguolide and the B ring in bryostatins.
