57357-24-1Relevant academic research and scientific papers
Metathetical redox reaction of (diacetoxyiodo)arenes and iodoarenes
Lauriers, Antoine Jobin-Des,Legault, Claude Y.
, p. 22635 - 22644 (2015)
The oxidation of iodoarenes is central to the field of hypervalent iodine chemistry. It was found that the metathetical redox reaction between (diacetoxyiodo)arenes and iodoarenes is possible in the presence of a catalytic amount of Lewis acid. This discovery opens a new strategy to access (diacetoxyiodo)arenes. A computational study is provided to rationalize the results observed.
Hypervalent iodine mediated synthesis of C-2 deoxy glycosides and amino acid glycoconjugates
Islam, Maidul,Tirukoti, Nishanth D.,Nandi, Shyamapada,Hotha, Srinivas
, p. 4470 - 4476 (2014/06/09)
A simple, efficient, and practical method for the synthesis of C-2 deoxy-2-iodo glycoconjugates in self-assembled structures was found using PhI(OCOR)2. 2-Iodo glycoserinyl esters were intramolecularly converted into 2-iodo serinyl glycosides which upon dehalogenation gave C-2 deoxy amino acid glycoconjugates.
