573693-08-0

Upstream product

• 55289-36-6 3-bromo-2-methylaniline 
• 31804-36-1 1-bromo-3-methoxy-2-methylbenzene 
• 55289-35-5 2-bromo-6-nitrotoluene 
• 7766-23-6 3-bromo-2-methylphenol 
• 573693-11-5 2-bromo-4-methoxy-3-methyl-1-nitro-benzene 

Downstream Products

• 573693-12-6 3-(2-bromo-4-methoxy-3-methyl-phenylamino)-4-methoxy-benzoic acid methyl ester 
• 1197358-98-7 C₁₄H₁₄BrNO 
• 573693-15-9 1,6-bis-(tert-butyl-diphenyl-silanyloxy)-8-(2,5-dimethyl-hex-1-enyl)-7-methyl-9H-carbazole-4-carboxylic acid methyl ester 
• 573693-16-0 [1,6-bis-(tert-butyl-diphenyl-silanyloxy)-8-(2,5-dimethyl-hex-1-enyl)-7-methyl-9H-carbazol-4-yl]-methanol 
• 573693-14-8 8-bromo-1,6-bis-(tert-butyl-diphenyl-silanyloxy)-7-methyl-9H-carbazole-4-carboxylic acid methyl ester 
• 886036-90-4 1,6-bis-(tert-butyl-diphenyl-silanyloxy)-8-(2,5-dimethyl-hept-1-enyl)-7-methyl-9H-carbazole-4-carboxylic acid methyl ester 
• 886036-91-5 [1,6-bis-(tert-butyl-diphenyl-silanyloxy)-8-(2,5-dimethyl-hept-1-enyl)-7-methyl-9H-carbazol-4-yl]-methanol 

Relevant academic research and scientific papers

Axially Chiral Dibenzazepinones by a Palladium(0)-Catalyzed Atropo-enantioselective C?H Arylation

Atropo-enantioselective C?H functionalization reactions are largely limited to the dynamic kinetic resolution of biaryl substrates through the introduction of steric bulk proximal to the axis of chirality. Reported herein is a highly atropo-enantioselective palladium(0)-catalyzed methodology that forges the axis of chirality during the C?H functionalization process, enabling the synthesis of axially chiral dibenzazepinones. Computational investigations support experimentally determined racemization barriers, while also indicating C?H functionalization proceeds by an enantio-determining CMD to yield configurationally stable eight-membered palladacycles.

Total synthesis of new lipocarbazoles isolated from the actinomycete tsukamurella pseudospumae acta 1857

New lipocarbazoles were synthesized by a sequence of three palladium-mediated coupling reactions and an improved protecting group strategy.

First total synthesis of the neuronal cell protecting carbazole alkaloid carbazomadurin A by sequential transition metal-catalyzed reactions

The highly oxygenated neuronal cell protecting carbazole alkaloid carbazomadurin A was synthesized in nine steps and 11% overall yield from isovanillic acid.