573703-12-5

Basic information

• Product Name: Benzeneacetic acid, a-[(diphenylphosphinyl)imino]-, (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl ester
• CAS NO: 573703-12-5
• Molecular Formula: C36H38NO3P
• Molecular Weight: 563.676
• Mol File: 573703-12-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzeneacetic acid, a-[(diphenylphosphinyl)imino]-, (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetic acid, a-[(diphenylphosphinyl)imino]-, (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl ester(573703-12-5)
• EPA Substance Registry System: Benzeneacetic acid, a-[(diphenylphosphinyl)imino]-, (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl ester(573703-12-5)

Safety Data

• Hazardous Substances Data: 573703-12-5(Hazardous Substances Data)

Upstream product

• 5994-87-6 diphenylphosphinamide 
• 88002-15-7 Phenylglyoxylsaeure-<(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)-1-cyclohexyl>ester 
• 611-73-4 Benzoylformic acid 
• 25726-04-9 phenylglyoxylyl chloride 

Downstream Products

• 573703-13-6 2-diphenylphosphinoylamino-2-phenyloct-3-enoic acid 5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl ester 
• 573703-16-9 (+)-(2R)-2-diphenylphosphinoylamino-2-phenyloctanoic acid methyl ester 
• 573703-15-8 (+)-(2R)-2-diphenylphosphinoylamino-2-phenyloct-3-enoic acid methyl ester 

Relevant articles and documents

Dimethylzinc-mediated addition of alkenylzirconocenes to α-keto and α-imino esters

(Matrix presented) Hydrozirconation of alkynes followed by in situ transmetalation to dimethylzinc and 1,2-addition to activated ketones and N-diphenylphosphinoylimines leads to tertiary allylic alcohols and amines in high overall yield. With 8-phenylmenthol as the chiral auxiliary, si-face attack proceeds in good to excellent diastereoselectivities.