57402-36-5Relevant articles and documents
Synthesis and Raman spectra of 3-deoxy-α-l-rhamnosides as model sugars of the Ascaris egg shell
Joly, Jean-Pierre,Roze, Frédéric,Banas, Sandrine,Quilès, Fabienne
, p. 3236 - 3241 (2010)
The synthesis of two 3-deoxy-α-l-rhamnosides (i.e., 3,6-dideoxy-l-arabino-hexopyranosides) as models of ascaroside natural products is reported. The present approach is based on a Ferrier rearrangement from l-rhamnal, epoxidation of the resulting glycal and reductive opening of the isolated β-epoxide. The 3-deoxy-α-rhamnoside linked to a long aglycone chain was used to ascertain by Raman vibrational spectroscopy the presence of this peculiar sugar in the inner shell of Ascaris eggs.
Amplifying (Im)perfection: The Impact of Crystallinity in Discrete and Disperse Block Co-oligomers
Van Genabeek, Bas,Lamers, Brigitte A. G.,De Waal, Bas F. M.,Van Son, Martin H. C.,Palmans, Anja R. A.,Meijer
supporting information, p. 14869 - 14872 (2017/10/31)
Crystallinity is seldomly utilized as part of the microphase segregation process in ultralow-molecular-weight block copolymers. Here, we show the preparation of two types of discrete, semicrystalline block co-oligomers, comprising an amorphous oligodimethylsiloxane block and a crystalline oligo-l-lactic acid or oligomethylene block. The self-assembly of these discrete materials results in lamellar structures with unforeseen uniformity in the domain spacing. A systematic introduction of dispersity reveals the extreme sensitivity of the microphase segregation process toward chain length dispersity in the crystalline block.
Palladium-catalyzed reduction of carboxylic acids to aldehydes with hydrosilanes in the presence of pivalic anhydride
Fujihara, Tetsuaki,Cong, Cong,Terao, Jun,Tsuji, Yasushi
supporting information, p. 3420 - 3424 (2013/12/04)
A palladium catalyst system that allows the reduction of carboxylic acids to the corresponding aldehydes with hydrosilanes as reducing agent and pivalic anhydride as an indispensable reagent has been developed. A simple mixture of commercially available bis(dibenzylideneacetone)palladium(0) [Pd(dba) 2], tri(para-tolyl)phosphane and methylphenylsilane realized the reduction of various aliphatic carboxylic acids as well as benzoic acids to aldehydes in good to high yields. Copyright