57405-01-3

Basic information

• Product Name: C₃₄H₂₃BrO₄
• CAS NO: 57405-01-3
• Molecular Weight: 575.458
• Mol File: 57405-01-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₄H₂₃BrO₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₄H₂₃BrO₄(57405-01-3)
• EPA Substance Registry System: C₃₄H₂₃BrO₄(57405-01-3)

Safety Data

• Hazardous Substances Data: 57405-01-3(Hazardous Substances Data)

Upstream product

• 6272-55-5 7-hydroxy-7,8,9,10-tetrahydrobenzopyrene 
• 17573-15-8 9,10-dihydro benzopyrene 
• 57405-00-2 (+/-)-7,8,9,10-Tetrahydrobenzopyrene-trans-7,8-diol dibenzoate 

Downstream Products

• 57404-88-3 (-)-trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene 
• 62314-67-4 (+/-)-trans-7,8-Dihydrobenzo[a]pyrene-7,8-diol 
• 60864-95-1 (-)-7R-trans-Benzopyrene-7,8-dihydrodiol 
• 57405-08-0 (+/-)-trans-7,8-Dihydrobenzopyrene-7,8-diol dibenzoate 

Relevant articles and documents

Preparation of Enantiomers of (+/-)-trans-7β,8α-Dihydroxy-9α,10α-epoxy-7,8,9,10-tetrahydrobenzopyrene

(+/-)-trans-7,8-Dihydroxy-7,8-dihydrobenzopyrene (VII), obtained from 7,8,9,10-tetrahydrobenzopyrene-7(8H)-one (I) by modifications and improvements of the reported procedures, has been converted into its di-(-) and (+)-menthoxyacetate derivatives in 82percent yield.The diastereomers have been separated by liquid chromatography on Lichrosorp Si 60 (30μ) column (100 cm x 1 cm dia.) using methylene chloride-ethyl acetate (99.4/0.6, v/v) as eluant.The enantiomers are liberated from the separated diastereomers by methanolysis with catalytic amount of sodium methoxide and converted into the enantiomers of (+/-)-trans-7β,8α-dihydroxy- 9α,10α-epoxy-7,8,9,10-tetrahydrobenzopyrene by m-chloroperbenzoic acid in an overall yield of 30percent.The CD and the UV spectra of the diastereomers and the enantiomers are reported.