57422-80-7Relevant academic research and scientific papers
Mechanistic Studies into the Oxidative Addition of Co(I) Complexes: Combining Electroanalytical Techniques with Parameterization
Sandford, Christopher,Fries, Lydia R.,Ball, Tyler E.,Minteer, Shelley D.,Sigman, Matthew S.
supporting information, p. 18877 - 18889 (2019/11/28)
The oxidative addition of organic electrophiles into electrochemically generated Co(I) complexes has been widely utilized as a strategy to produce carbon-centered radicals when cobalt is ligated by a polydentate ligand. Changing to a bidentate ligand prov
Mechanistic analysis of oxidative C-H cleavages using inter- and intramolecular kinetic isotope effects
Jung, Hyung Hoon,Floreancig, Paul E.
experimental part, p. 10830 - 10836 (2010/02/28)
A series of monodeuterated benzylic and allylic ethers were subjected to oxidative carbon-hydrogen bond cleavage to determine the impact of structural variation on intramolecular kinetic isotope effects in DDQ-mediated cyclization reactions. These values
Decatungstate-mediated radical reactions of C6o with substituted toluenes and anisoles: A new photochemical functionalization strategy for fullerenes
Tzirakis, Manolis D.,Orfanopoulos, Michael
supporting information; experimental part, p. 873 - 876 (2009/04/07)
A convenient, highly efficient, decatungstate-mediated chemical methodology to functionalize fullerenes is demonstrated. A variety of radicals have been generated by the photochemical interaction of tetrabutylammonium decatungstate [(n-Bu4N)su
Reactive Intermediates from the Solvolysis of Mutagenic O-Alkyl N-Acetoxybenzohydroxamates
Bonin, Antonio M.,Glover, Stephen A.,Hammond, Gerard P.
, p. 1173 - 1180 (2007/10/02)
Mutagenic O-(para-substituted benzyl) N-acetoxybenzohydroxamates undergo acid-catalysed solvolysis in aqueous acetonitrile but three is a change in mechanism from AA11 to E1 on going from para electron-withdrawing substituents to para +M electron-donating groups.The former permit the formation of a discrete nitrenium ion intermediate whereas the latter promote a concerted elimination of a resonance stabilized benzyl carbocation.
