57427-48-2Relevant articles and documents
Deuterium Kinetic Isotope Effects in the 1,4-Dimethylenecyclohexane Boat Cope Rearrangement
Gajewski, Joseph J.,Jimenez, Jose Leonardo
, p. 468 - 474 (2007/10/02)
In order to examine the extent of bond making in the boat-like 3,3-sigmatropic shift transition states, trans-2,3-dimethyl-1,4-dimethylenecyclohexane (T) and its exomethylene tetradeuteria derivative (TXD) were prepared.The 3,3-shift of TXD at 305 deg C r