57441-06-2Relevant academic research and scientific papers
Phosphine/Photoredox Catalyzed Anti-Markovnikov Hydroamination of Olefins with Primary Sulfonamides via α-Scission from Phosphoranyl Radicals
Chinn, Alex J.,Sedillo, Kassandra,Doyle, Abigail G.
supporting information, p. 18331 - 18338 (2021/11/10)
New strategies to access radicals from common feedstock chemicals hold the potential to broadly impact synthetic chemistry. We report a dual phosphine and photoredox catalytic system that enables direct formation of sulfonamidyl radicals from primary sulf
Synthesis of Tricyclohexylphosphonium Bromides from an Air-Stable Phosphine Derivative
Bestmann, Hans Juergen,Doetzer, Reinhard
, p. 204 - 205 (2007/10/02)
Reaction of tricyclohexylphosphine-carbon disulfide complex 5 with primary alkyl bromides 4 produces tricyclohexylphosphonium bromides 1 in good yields, making isolation of the phosphine 3 unnecessary.In two cases for 4g, h, rearranged products were obtai
