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Tricyclohexyl(dithiocarboxylato)phosphonium is a phosphonium salt with the chemical formula (C6H11)3P(S2CRO), characterized by its dithiocarboxylate anion. It is a versatile reagent in organic synthesis, known for its role as a phase transfer catalyst that facilitates the transfer of reactants between immiscible phases.

70165-72-9

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70165-72-9 Usage

Uses

Used in Organic Synthesis:
Tricyclohexyl(dithiocarboxylato)phosphonium is used as a reagent in organic synthesis for its ability to catalyze various reactions, enhancing the efficiency and selectivity of the processes.
Used in Coordination Chemistry:
In the field of coordination chemistry, tricyclohexyl(dithiocarboxylato)phosphonium is employed as a ligand or a catalyst, contributing to the formation of complex structures and compounds.
Used in Materials Science:
Tricyclohexyl(dithiocarboxylato)phosphonium is utilized in materials science for its potential applications in the synthesis and modification of materials with specific properties.
Used in Industrial Catalysis:
tricyclohexyl(dithiocarboxylato)phosphonium is studied for its potential use in industrial catalysis, where it could improve the efficiency of chemical processes in large-scale manufacturing.
Used in Polymerization Reactions:
Tricyclohexyl(dithiocarboxylato)phosphonium is used as a stabilizing agent in polymerization reactions, helping to control the reaction kinetics and produce polymers with desired characteristics.

Check Digit Verification of cas no

The CAS Registry Mumber 70165-72-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,0,1,6 and 5 respectively; the second part has 2 digits, 7 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 70165-72:
(7*7)+(6*0)+(5*1)+(4*6)+(3*5)+(2*7)+(1*2)=109
109 % 10 = 9
So 70165-72-9 is a valid CAS Registry Number.
InChI:InChI=1/C19H33PS2/c21-19(22)20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2/p+1

70165-72-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name tricyclohexylphosphaniumylmethanedithioate

1.2 Other means of identification

Product number -
Other names tricyclohexylphosphonium dithiocarboxylate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:70165-72-9 SDS

70165-72-9Relevant academic research and scientific papers

Assessing the potential of zwitterionic NHOCS2 adducts for probing the stereoelectronic parameters of N-heterocyclic carbenes

Delaude, Lionel,Demonceau, Albert,Wouters, Johan

experimental part, p. 1882 - 1891 (2009/10/30)

Five imidazol(in)ium-2-dithiocarboxylates bearing cyclo-hexyl, mesityl, or 2,6-diisopropylphenyl substituents on their nitrogen atoms were prepared from the corresponding N-heterocyclic carbenes (NHCs) by reaction with carbon disul-fide. They were charact

Synthesis of Cationic Palladium(II) and Platinum(II) Complexes with a Monodentate Trialkylphosphoniumditiocarboxylate Ligand: Molecular Structure of trans-ClO4*CHCl3

Uson, Rafael,Fornies, Juan,Navarro, Rafael,Uson, Miguel A.,Garcia, Maria P.,Welch, Alan J.

, p. 345 - 350 (2007/10/02)

Reaction of trans- with the zwitterion S2C-PR'3 affords the complexes trans-ClO4 (M= Pd; R3=R'3= Et3, Bu3 or Et2Ph; R= Bu, R'= cyclo-C6H11; R= Ph, R'= Et or cyclo-C6H11; M= Pt, R=R'= Et or Bu). trans-ClO4 is also given by reaction of ClO4 with CS2.Reaction of (bipy= 2,2'-bipyridyl) with S2C-PR'3 affords ClO4 (M=Pd or Pt; R'=Et, Bu, or cyclo-C6A11).A crystallographic study of trans-ClO4 (as its 1:1 chloroform solvate) shows that the cation contains a unidentate triethylphosphoniumdithiocarboxylate ligand, and 31P n.m.r. spectra of all products with two terminal phosphine ligands are consistent with trans stereochemistries.Crystals of trans-ClO4*CHCl3 are monoclinic, space group P21/a, with a=14.596 5(18), b=15.356(3), c=19.324 2(16) angstroem, β=109.257(8) deg, and Z=4.Using 4 093 amplitudes the structure has been refined to R=0.1049.The non-bonding Pd...S distance is 3.644(4) angstroem.

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