57449-06-6Relevant academic research and scientific papers
Hydrosilation of dienes catalyzed by CP*2NdCH(SiMe3)2
Onozawa, Shun-Ya,Sakakura, Toshiyasu,Tanaka, Masato
, p. 8177 - 8180 (1994)
Cp*2NdCH(SiMe3)2 efficiently catalyzes hydrosilation of 1,3-, 1,5-, and 1,6-dienes under mild conditions with unusual selectivities as compared with later transition metal-catalyzed reactions; hydrosilation of isoprene aff
Control of Selectivity through Synergy between Catalysts, Silanes, and Reaction Conditions in Cobalt-Catalyzed Hydrosilylation of Dienes and Terminal Alkenes
Raya, Balaram,Jing, Stanley,Balasanthiran, Vagulejan,Rajanbabu
, p. 2275 - 2283 (2017/06/01)
Readily accessible (i-PrPDI)CoCl2 [i-PrPDI = 2,6-bis(2,6-diisopropylphenyliminoethyl)pyridine] reacts with 2 equiv of NaEt3BH at -78 °C in toluene to generate a catalyst that effects highly selective anti-Markov
