574703-55-2Relevant academic research and scientific papers
First examples of AuI-X-AgI halonium cations (X = Cl and Br)
Zhang, Ke,Prabhavathy, Janardhana,Yip, John H. K.,Koh, Lip Lin,Tan, Geok Kheng,Vittal, Jagadese J.
, p. 8452 - 8453 (2003)
Novel {[(μ-PAnP)(AuX)2]2Ag}+SbF6- halonium ions (X = Cl, Br; PAnP = 9,10-bis(diphenylphosphino)anthracene) were synthesized from the reactions between (μ-PAnP)(AuX)2 and 1/2 mol equiv of AgSbF6. The compounds feature an unprecedented distorted Au4X4 dodecahedron which encapsulates a silver(I) ion at its center. The halonium ions are stabilized by collective actions of metallophilic Au-Ag, aromatic π-π, and Ag-X interactions. Copyright
