57485-08-2Relevant articles and documents
New Routes Towards Halogeno Complexes of Gold by Halide Exchange from . Crystal and Molecular Structure of Triphenylmethylium Tetrachloroaurate(III),
Dell'Amico, Daniela Belli,Calderazzo, Fausto,Morvillo, Antonio,Pelizzi, Giancarlo,Robino, Pierluigi
, p. 3009 - 3016 (2007/10/02)
Anhydrous and AuI can be obtained by halide exchange from with RX (X = Br or I, R = H or alkyl).The addition of to CPh3Cl produces the ionic derivative whose crystal and molecular structure has been determined by X-ray diffraction.Crystal data: space group P21/c, a = 8.225(3), b = 14.671(6), c = 16.738(8) Angstroem, β = 97.85(2) deg and Z = 4.Other organic chlorides RCl (R = Pr, SiMe3 or But) react with with a partial reduction to the mixed-valence chloride .Addition of to anhydrous iron(III) chloride produced a mass-spectrometrically active mixed iron-gold species.
New entries to halo- and halo-carbonyl complexes of gold
Dell'Amico, Daniela Belli,Calderazzo, Fausto,Robino, Pierluigi,Segre, Annalaura
, p. 51 - 52 (2007/10/02)
Gold(I) halides have been obtained from Au2Cl6: a) with cyclohexene as halogen acceptor (AuCl); b) by halide exchange with i-Pr-Br, followed by treatment with cyclohexene at low temperature (AuBr); c) by halide exchange with i-Pr-I at room temperature (AuI).Carbonylation of AuBr in dichloromethane or treatment of Au2Br6 with CO and cyclohexene in 1,2-dibromoethane yielded AuBr(CO), characterized by IR and 13C NMR spectra in solution, the latter at low temperature