57497-09-3Relevant articles and documents
Nickel-catalyzed ring-opening hydroacylation of methylenecyclopropanes: Synthesis of γ,δ-unsaturated ketones from aldehydes
Taniguchi, Hiroki,Ohmura, Toshimichi,Suginome, Michinori
, p. 11298 - 11299 (2011/02/28)
(Chemical Equation Presented) A nickel-catalyzed intermolecular hydroacylation of methylenecyclopropanes (MCPs) has been developed. The reaction proceeds with stereospecific cleavage of the proximal C-C bond of the cyclopropane ring to give γ,δ-unsaturate