57519-79-6

Upstream product

• 82650-66-6 2,3-Dicyano-2-methylsulfanyl-3,3-diphenyl-propionic acid methyl ester 
• 39950-39-5 2-bromo-2,3-dicyano-3,3-diphenyl-propionic acid methyl ester 
• 119072-55-8 tert-butylisonitrile 

Downstream Products

• 57519-76-3 3,3-dibenzyl-4-[(E)-5-(cyano-diphenyl-methyl)-6-oxo-4-(triphenyl-λ⁵-phosphanylideneamino)-3,6-dihydro-[1,3]oxazin-2-ylidene]-1-methyl-pyrrolidine-2,5-dione 
• 56655-98-2 3-cyano-2-[5-(cyano-diphenyl-methyl)-6-oxo-4-(triphenyl-λ⁵-phosphanylideneamino)-3,6-dihydro-[1,3]oxazin-2-ylidene]-3,3-diphenyl-propionic acid methyl ester 
• 82650-65-5 2,3-Dicyano-3,3-diphenyl-2-phenylsulfanyl-propionic acid methyl ester 
• 82650-36-0 3-Cyano-2-(methylsulfanylmethylimino-methylene)-3,3-diphenyl-propionic acid methyl ester 
• 82650-37-1 2,3-Dicyano-2-methylsulfanylmethyl-3,3-diphenyl-propionic acid methyl ester 
• 65739-17-5 2,3-Dicyano-2-(3-cyano-2-methoxycarbonyl-3,3-diphenyl-propenylideneamino)-3,3-diphenyl-propionic acid methyl ester 
• 82939-94-4 methyl 3-tert-butylimino 2-cyano 2-diphenylcyanomethyl 3-methylthiopropanoate 
• 82939-95-5 methyl 3-tert-butylimino 2-cyano 2-(diphenylcyanomethyl) 3-phenylthiopropanoate 
• 82650-54-2 3-Cyano-2-[(1-methylsulfanyl-ethylimino)-methylene]-3,3-diphenyl-propionic acid methyl ester 
• 82650-49-5 2,3-Dicyano-2-ethylsulfanylmethyl-3,3-diphenyl-propionic acid methyl ester 
• 82650-48-4 3-Cyano-2-(ethylsulfanylmethylimino-methylene)-3,3-diphenyl-propionic acid methyl ester 
• 57766-92-4 N-<(Methylthio)-phenylmethyl>-succinimid 
• 82650-67-7 2,3-Dicyano-2-(methylsulfanyl-phenyl-methyl)-3,3-diphenyl-propionic acid methyl ester 
• 82650-64-4 2-Chloro-2,3-dicyano-3,3-diphenyl-propionic acid methyl ester 

Relevant academic research and scientific papers

UNCATALYZED INSERTION REACTION OF ISOCYANIDES INTO A CARBON-SULFUR BOND

Tert-butylisocyanide and tert-octylisocyanide insert into the carbone-sulfur bond of activated sulfides 2 yielding thioimidates 5 which rearrange to enamines 6.

REACTION DES COMPOSES A HALOGENE POSITIF AVEC LES COMPLEXES 1:1 NITRATE D'ARGENT-TRIPHENYLPHOSPHINE OU PHOSPHITE DE TRIMETHYLE

The reaction of α-bromo α-cyanoesters, α-bromo α-cyanonitriles and α-bromo α-cyanoimides with silver nitrate-triphenylphosphine or trimethylphosphite complexes brings about replacement of positive halogen by a nitro group in mild conditions.