65739-17-5Relevant academic research and scientific papers
ADDITION NUCLEOPHILE DES ANIONS D'ESTERS α-CYANOACETIQUES SUR LES CATIONS SUCCINIMIDOSULFONIUM. FRAGMENTATION IONIQUE OU RADICALAIRE DES ?-SULFURANES INTERMEDIAIRES
Morel, G.,Lemoing-Orliac, M. A.,Khamsitthideth, S.,Foucaud, A.
, p. 527 - 537 (2007/10/02)
Reactions of substituted cyanoacetate anions 4 with S,S-dialkylsuccinimidosulfonium salts resulted generally in the formation of N-alkylthiomethylketenimines and α-alkylthiomethylesters.Coupling products were also obtained with anion 4d and only observed in the case of methyl phenylcyanoacetate anion 4b.The results were interpreted by the formation of instable ?-sulfurane intermediates.Homolytic cleavage of these intermediates gave radical pairs, then the coupling products.Heterolytic cleavage gave new sulfonium salts which rearranged via sulfonium ylides.
Reactions of Triphenylphosphine- and Trialkyl Phosphite-Silver Nitrate Complexes with Positive Halogen Compounds. Synthesis of α-Nitro Nitriles
Ketari, Rachid,Foucaud, Andre
, p. 4498 - 4501 (2007/10/02)
The reaction of α-bromo-α-cyano esters, α-bromo-α-cyano nitriles, and α-bromo-α-cyano imides with triphenylphosphine- or trialkyl phosphite-silver nitrate complexes leads to replacement of the positive bromine atom by a nitro group under mild conditions.I
