5754-91-6Relevant academic research and scientific papers
Synthesis of cyclic dinitramines useful as explosive and propellant ingredients, gas generants and in other ordnance applications
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, (2008/06/13)
A new one-step synthesis of cyclic 1,3 dinitramines is disclosed. This syesis utilizes a solution of N2 O5 in 100% nitric acid as the nitrolyzing media. The polynitramines thus produced find utility as explosive and propellant ingredients, gas generants and in other ordnance applications.
An Alternate Synthesis of Cyclic 1,3-Dinitramines
Willer, Rodney L.,Atkins, Ronald L.
, p. 5147 - 5150 (2007/10/02)
An alternate synthesis for cyclic 1,3-dinitramines has been developed.The new method involves the trapping of an in situ generated cyclic aminal with nitrous acid to generate a cyclic 1,3-dinitrosamine, which is subsequently converted to the cyclic 1,3-dinitramine by treatment with 100percent nitric acid or solutions of N2O5 in 100percent nitric acid.This alternate synthesis is superior for the synthesis of 5- and some 6-membered cyclic 1,3-dinitramines but not for 7-membered compounds.
