575433-00-0Relevant academic research and scientific papers
Enantiospecific synthesis of vicinal stereogenic tertiary and quaternary centers by combination of configurationally-trapped radical pairs in crystalline solids
Ellison, Martha E.,Ng, Danny,Dang, Hung,Garcia-Garibay, Miguel A.
, p. 2531 - 2534 (2003)
(Matrix presented) Photochemical irradiation of crystalline (2R,4S)-2-carbomethoxy-4-cyano-2,4-diphenyl-3-butanone 1 led to highly efficient decarbonylation reactions. Experiments with optically pure and racemic crystals showed that the intermediate radic
