575451-86-4Relevant academic research and scientific papers
The synthesis of red dyes based on diketo-pyrrolo-pyrrole chromophore to improve heat stability and solubility for colour filter fabrication
Kim, Tae-Heon,Lee, Byung-Jun,An, Sung-Ok,Lee, Joo-Hong,Choi, Jae-Hong
, (2019/12/06)
To replace the conventional red pigment derived from diketo-pyrrolo-pyrrole by new red dyes prepared in this research, an acetylene linkage was introduced between N-alkyl diketo-pyrrolo-pyrrole and naphthalimidyl moiety. TGA analyses and solubility measur
Phenothiazin-: N -yl-capped 1,4-diketo-3,6-diphenylpyrrolo[3,4- c] pyrrole exhibiting strong two-photon absorption and aggregation-enhanced one- and two-photon excitation red fluorescence
Zhang, Kai,Liu, Zhongwei,Ying, Shian,Chen, Mingshuai,Xue, Shanfeng,Zhang, Haichang,Yang, Wenjun
, p. 30610 - 30617 (2017/07/10)
Water-soluble or water-dispersible two-photon dyes with strong fluorescence and large two-photon absorption (2PA) cross sections are very desirable for nano- and bio-photonics, but are still scarce. Herein, a new 1,4-diketo-3,6-diphenylpyrrolo[3,4-c]pyrrole derivative end-capped with two phenothiazin-N-yl donors (PDPP) is synthesized and its one- and two-photon optical properties are investigated in both solution and aqueous dispersions. The results show that PDPP exhibits solvent-independent one-photon solution absorption and emission properties with low fluorescence quantum yields, but strong red fluorescence in both aqueous dispersion and the crystalline state. This aggregation-enhanced emission (AEE) effect enables PDPP to have not only large 2PA cross sections but also a remarkably enhanced two-photon fluorescence action cross section in aqueous dispersions. Thus, 2PA-active PDPP is a promising candidate for two-photon science and technology.
New cyano-substituted organic dyes containing different electrophilic groups: Aggregation-induced emission and large two-photon absorption cross section
Zhou, Haitao,Huang, Wei,Ding, Li,Cai, Shengyun,Li, Xin,Li, Bo,Su, Jianhua
, p. 7050 - 7056 (2015/03/14)
Three aggregation-induced emission active dyes (3a-c) were synthesized and their one- and twophoton absorption properties have been investigated. They were all found to be weakly fluorescent in THF solution, while they exhibited dramatic fluorescence enhancement in water/THF mixtures. The solid fluorescence of 3a-c was recorded and their fluorescence quantum efficiency (φf) values were determined to be 8.0%, 8.1%, and 16.4%, respectively. Moreover, the two-photon absorption (2PA) crosssections (σ) of 3a-c were measured and 3a showed the highest value of 702 GM The excellent aggregation-induced emission and 2PA properties provide a promising alternative for biophotonic materials.
