575457-73-7

Upstream product

• 3601-36-3 methyl 2,3,6-tri-O-benzoyl-α-D-galactopyranoside 
• 3396-99-4 methyl α-D-galactopyranoside 
• 10257-28-0 D-Galactose 
• 74593-34-3 methyl 4-azido-2,3,6-tri-O-benzoyl-4-deoxy-α-D-glucopyranoside 
• 79580-70-4 Methyl 2,3,6-tri-O-benzoyl-4-O-trifluoromethanesulfonyl-α-D-galactopyranoside 
• 575457-72-6 C₂₆H₂₃N₅O₉ 

Downstream Products

• 575457-75-9 (2S,3S,4S,5R,6R)-3-Azido-4,5-bis-benzoyloxy-6-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-pyran-2-carboxylic acid 

Relevant academic research and scientific papers

An efficient synthesis of gougerotin and related analogues using solid- and solution-phase methodology

(Chemical Equation Presented) The first solid-phase synthesis of the natural product gougerotin has been accomplished. The synthetic route is versatile and allows for diversification at position C-4 of the heterocycle, C-6′ of the sugar ring, and both residues of the peptidic moiety at N-4′ in a parallel fashion.

Total synthesis method for xinaomycin

The invention belongs to the technical field of pharmaceutical chemistry and organic synthesis, and aims to provide a chemical total synthesis method for xinaomycin. The method comprises the steps of:using D-galactose and the like as raw materials, firstly carrying out 8 steps of reactions to obtain a compound 14, then performing condensation on the compound 14 and uracil to obtain a compound 15,performing 4 steps of reactions to obtain a compound 19, performing condensation on the compound 19 and a compound 6 to obtain a compound 20, and finally removing an ester protecting group and a Cbzprotecting group in turn, so as to obtain the natural product xinaomycin. The total synthesis method of the present invention is a method for synthesizing the natural product xinaomycin for the firsttime. The total synthesis method has the advantages of high product purity, low cost, simple operation and the like.