5755-55-5Relevant academic research and scientific papers
Visible-Light-Driven Photocatalytic Initiation of Radical Thiol-Ene Reactions Using Bismuth Oxide
Fadeyi, Olugbeminiyi O.,Mousseau, James J.,Feng, Yiqing,Allais, Christophe,Nuhant, Philippe,Chen, Ming Z.,Pierce, Betsy,Robinson, Ralph
supporting information, p. 5756 - 5759 (2015/12/11)
A nontoxic and inexpensive photocatalytic initiation of anti-Markovnikov hydrothiolation of olefins using visible light is reported. This method is characterized by low catalyst loading, thereby enabling a mild and selective method for radical initiation in thiol-ene reactions between a wide scope of olefins and thiols.
Photocatalytic initiation of thiol-ene reactions: Synthesis of thiomorpholin-3-ones
Keylor, Mitchell H.,Park, James E.,Wallentin, Carl-Johan,Stephenson, Corey R.J.
, p. 4264 - 4269 (2014/06/09)
A mild, redox neutral photocatalytic method for alkene hydrothiolation is reported. Utilizing visible-light activation, catalytic radical initiation is achieved with the transition metal complex Ru(bpy)3Cl2, enabling rapid access to a diverse set of thiol-ene coupled products in excellent yield. On the basis of a strong observed background reaction in some cases, we have developed a solvent-free, Lewis acid-promoted tandem amidation-hydrothiolation sequence, providing thiomorpholin-3-ones in a one-pot operation from commercially available materials.
A novel one pot synthesis of benzyl sulfides: Samarium-induced, benzyl bromide mediated reduction of alkyl thiocyanates and diaryl disulfides in methanol
Zhan, Zhuang-Ping,Lang, Kai
, p. 443 - 444 (2007/10/03)
A convenient synthesis of benzyl Sulfides by the treatment of alkyl thiocyanates or diaryl disulfides with metallic samarium and benzyl bromide in methanol has been developed.
Assembly of a series of malarial glycosylphosphatidylinositol anchor oligosaccharides
Kwon, Yong-Uk,Soucy, Regina L.,Snyder, Daniel A.,Seeberger, Peter H.
, p. 2493 - 2504 (2007/10/03)
We report an efficient and convergent synthesis of a series of oligosaccharides comprised of the malaria GPI glycan (2 a), a promising anti-malaria vaccine candidate currently in preclinical trials and several related oligosaccharide sequences (3-8) that
