5757-79-9Relevant academic research and scientific papers
Enantioselective Synthesis of Trisubstituted Allenes via Cu(I)-Catalyzed Coupling of Diazoalkanes with Terminal Alkynes
Chu, Wen-Dao,Zhang, Lei,Zhang, Zhikun,Zhou, Qi,Mo, Fanyang,Zhang, Yan,Wang, Jianbo
supporting information, p. 14558 - 14561 (2016/11/18)
A highly enantioselective synthesis of trisubstituted allenes has been achieved through Cu(I)-catalyzed cross-coupling of aryldiazoalkanes and terminal alkynes with chiral bisoxazoline ligands. Alkynyl migratory insertion of Cu(I) carbene is proposed as t
