57585-12-3Relevant academic research and scientific papers
Synthesis of Allenyl Esters by Horner-Wadsworth-Emmons Reactions of Ketenes Mediated by Isopropylmagnesium Bromide
Sano, Shigeki,Matsumoto, Tomoya,Yano, Teppei,Toguchi, Munehisa,Nakao, Michiyasu
, p. 2135 - 2138 (2015)
The synthesis of conjugated allenyl esters (tri-substituted allenes) was achieved by magnesium(II)-mediated Horner-Wadsworth-Emmons reaction of methyl bis(2,2,2-trifluoroethyl)phosphonoacetate with disubstituted ketenes. In addition, a novel access to α-fluorinated allenyl carboxamides (tetrasubstituted allenes) is presented.
