57662-91-6Relevant academic research and scientific papers
Hydrogenation of sulfoxides to sulfides under mild conditions using ruthenium nanoparticle catalysts
Mitsudome, Takato,Takahashi, Yusuke,Mizugaki, Tomoo,Jitsukawa, Koichiro,Kaneda, Kiyotomi
, p. 8348 - 8351 (2014)
The first demonstration of the hydrogenation of sulfoxides under atmospheric H2 pressure is reported. The highly efficient reaction is facilitated by a heterogeneous Ru nanoparticle catalyst. The mild reaction conditions enable the selective hydrogenation of a wide range of functionalized sulfoxides to the corresponding sulfides. The high redox ability of RuO x nanoparticles plays a key role in the hydrogenation.
THE USE OF PHOSPHONODITHIOFORMATES FOR THE SYNTHESIS OF KETENE DITHIOACETALS
Bulpin, Andrew,Masson, Serge,Sene, Aboubacary
, p. 3415 - 3418 (2007/10/02)
Phosphonodithioformates 1 undergo thiophilic addition with both organolithium and Grignard reagents to give metallated dithioacetals of formyl-phosphonates 2, available for protonation, alkylation or use in Wittig-Horner reactions.Oxidation of 1 by meta-c
