57665-45-9Relevant articles and documents
CHEMOSELEKTIVE MONO- UND DISILYLETHERBILDUNG AUS TERTIAEREN UND SEKUNDAEREN SILANEN
Horner, Leopold,Mathias, Johann
, p. 155 - 174 (2007/10/02)
Tertiary and secondary silanes are O-selective.With alcohols the corresponding silyl ethers are formed.Cesium fluoride/imidazole)CsF/Im) is a better activating system than CsF alone.Primary OH groups are silylated remarkably faster under CsF/Im activation
Base Induced 1,2-Hydride Shifts from Silicon to Carbon: "Anomalous" Substitution reactions with (Halomethyl)diorganosilanes
Tacke, Reinhold,Lange, Hartwig,Attar-Bashi, Moayad T.
, p. 1946 - 1951 (2007/10/02)
(C6H5)2Si(H)CH2X (1a: X = Cl; 1b: X = I) and C6H5(CH3)Si(H)CH2Cl (10) react with LiOCH2CH2N(CH3)2 (2b) to give the alkoxysilanes (C6H5)2Si(CH3)OCH2CH2N(CH3)2 (5) and C6H5(CH3)2SiOCH2CH2N(CH3)2 (12), respectively.The formation of these unexpected reaction