5769-16-4

Upstream product

• 6325-93-5 p-nitrobenzenesulfonamide 
• 111-36-4 n-butyl isocyanide 
• 201230-82-2 carbon monoxide 
• 149552-43-2 [N-(nosyl)imino]phenyliodinane 
• 75-44-5 phosgene 

Downstream Products

• 5992-24-5 N-<4-Nitro-benzolsulfonyl>-N'-<4t-phenyl-cyclohexyl>-harnstoff 
• 3337-70-0 methyl ((4-nitrophenyl)sulfonyl)carbamate 
• 1185060-02-9 (+/-)-7-oxonon-1-en-5-yl 4-nitrophenylsulfonylcarbamate 
• 1185060-12-1 (+/-)-(E)-undeca-1,8-dien-5-yl 4-nitrophenylsulfonylcarbamate 
• 1185060-21-2 (+)-(3S,4S)-4-(benzyloxy)hept-6-en-3-yl 4-nitrophenylsulfonylcarbamate 
• 1237479-06-9 (-)-tert-butyl ((2R,3R)-1-(tert-butyldimethylsilyl)-2-((R)-1-((((4-nitrophenyl)sulfonyl)carbamoyl)oxy)but-3-en-1-yl)-4-oxoazetidin-3-yl)carbamate 
• 1448804-71-4 (+/-)-(E)-5-methyl-4-(3-((4-nitrophenyl)sulfonyl)ureido)hex-2-en-1-yl acetate 
• 1448804-70-3 C₁₉H₂₁N₃O₆S 
• 1448804-68-9 (+/-)-(E)-N-((2-methylhex-4-en-3-yl)carbamoyl)-4-nitrobenzenesulfonamide 
• 1448804-67-8 (+/-)-N-((1-(4-methoxyphenyl)-2-methylpent-4-en-2-yl)carbamoyl)-4-nitrobenzenesulfonamide 
• 1448804-63-4 (+/-)-N-((2,2-dimethylhex-5-en-3-yl)carbamoyl)-4-nitrobenzenesulfonamide 
• 1448804-62-3 (+/-)-N-((6-methylhept-1-en-4-yl)carbamoyl)-4-nitrobenzenesulfonamide 
• 1448804-61-2 (+/-)-N-(hex-5-en-3-ylcarbamoyl)-4-nitrobenzenesulfonamide 
• 1448804-59-8 (+/-)-N-((2-methylhex-5-en-3-yl)carbamoyl)-4-nitrobenzenesulfonamide 

Relevant academic research and scientific papers

Phosphine-Catalyzed (4+1) Annulation: Rearrangement of Allenylic Carbamates to 3-Pyrrolines through Phosphonium Diene Intermediates

We have developed a phosphine-catalyzed (4+1) annulative rearrangement for the preparation of 3-pyrrolines from allenylic carbamates via phosphonium diene intermediates. We employed this methodology to synthesize an array of 1,3-disubstituted- and 1,2,3-t

Catalyst-controlled C-O versus C-N allylic functionalization of terminal olefins

The divergent synthesis of syn-1,2-aminoalcohol or syn-1,2-diamine precursors from a common terminal olefin has been accomplished using a combination of palladium(II) catalysis with Lewis acid cocatalysis. Palladium(II)/bis-sulfoxide catalysis with a silver triflate cocatalyst leads for the first time to anti-2-aminooxazolines (C-O) in good to excellent yields. Simple removal of the bis-sulfoxide ligand from this reaction results in a complete switch in reactivity to afford anti-imidazolidinone products (C-N) in good yields and excellent diastereoselectivities. Mechanistic studies suggest the divergent C-O versus C-N reactivity from a common ambident nucleophile arises due to a switch in mechanism from allylic C-H cleavage/functionalization to olefin isomerization/oxidative amination.

Diversification of a β-lactam pharmacophore via allylic C-H amination: Accelerating effect of Lewis acid co-catalyst

This report describes the use of Pd(II)/bis-sulfoxide 1 catalyzed intra- and intermolecular allylic C-H amination reactions to rapidly diversify structures containing a sensitive β-lactam core similar to that found in the monobactam antibiotic Aztreonam.

Allylic C-H amination for the preparation of syn-1,3-amino alcohol motifs

A highly selective and general Pd/sulfoxide-catalyzed allylic C-H amination reaction en route to syn-1,3-amino alcohol motifs is reported. Key to achieving this reactivity under mild conditions is the use of electron-deficient N-nosyl carbamate nucleophil

Palladium-catalyzed carbonylation of (arylsulfonyliminoido)-benzenes to arylsulfonyl isocyanates

In the presence of palladium complexes as catalysts, carbonylation of (arylsulfonyliminoiodo)benzenes to arylsulfonyl isocyanates can be accomplished with 50-80% yield.

Phosphonoureide and phosphonothioureide anthelmintics

This invention relates to novel anthelmintic compounds containing an arylene or divalent heterocyclic ring whose free valences are satisfied by 1. a disubstituted phosphoryl ureido or thioureido group and 2. an amino group or a substituted amido or thioamido group, To compositions containing them, and to methods of using them for the treatment of intestinal parasites in mammals and birds.