57704-00-4

Basic information

• Product Name: 4-Thiazolidinecarboxylic acid, 3-benzoyl-2,2-dimethyl-, (R)-
• CAS NO: 57704-00-4
• Molecular Formula: C13H15NO3S
• Molecular Weight: 265.333
• Mol File: 57704-00-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-Thiazolidinecarboxylic acid, 3-benzoyl-2,2-dimethyl-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Thiazolidinecarboxylic acid, 3-benzoyl-2,2-dimethyl-, (R)-(57704-00-4)
• EPA Substance Registry System: 4-Thiazolidinecarboxylic acid, 3-benzoyl-2,2-dimethyl-, (R)-(57704-00-4)

Safety Data

• Hazardous Substances Data: 57704-00-4(Hazardous Substances Data)

Upstream product

• 67089-92-3 L-(-)-2,2-dimethylthiazolidine-4-carboxylic acid hydrochloride salt 
• 98-88-4 benzoyl chloride 

Downstream Products

• 67089-88-7 (R)-4-benzoyl-5-methyl-3,4-dihydro-2H-[1,4]thiazine-3-carboxylic acid methyl ester 
• 67089-91-2 (R)-3-benzoyl-4-(6-chloro-purin-9-ylmethyl)-2,2-dimethyl-thiazolidine 
• 67089-89-8 (4R)-3-benzoyl-5t-benzoyloxy-2,2-dimethyl-thiazolidine-4r-carboxylic acid methyl ester 
• 67089-90-1 (R)-3-benzoyl-4-hydroxymethyl-2,2-dimethyl-thiazolidine 
• 67089-86-5 (4R)-3-benzoyl-2,2-dimethyl-1t-oxo-1λ⁴-thiazolidine-4r-carboxylic acid methyl ester 
• 1334521-44-6 SS-((2R,3R)-3-benzamido-4-oxoazetidin-2-yl)O-methyl carbon(dithioperoxoate) 
• 1334521-85-5 (1R,5R)-2-benzoyl-3,3-dimethyl-4-thia-2,6-diazabicyclo[3.2.0]heptan-7-one 
• 1334521-42-4 SS-((2R,3R)-3-benzamido-1-(benzyloxy)-4-oxoazetidin-2-yl) O-methyl carbon-(dithioperoxoate) 
• 1334521-76-4 benzyl 2-(((1R,5R)-2-benzoyl-3,3-dimethyl-7-oxo-4-thia-2,6-diazabicyclo[3.2.0]heptan-6-yl)oxy)acetate 
• 1334521-72-0 (1R,5R)-2-benzoyl-6-(benzyloxy)-3,3-dimethyl-4-thia-2,6-diazabicyclo[3.2.0]heptan-7-one 
• 1334521-40-2 (1R,5R)-2-benzoyl-6-methoxy-3,3-dimethyl-4-thia-2,6-diazabicyclo[3.2.0]heptan-7-one 
• 1334521-62-8 benzyl 2-(((4R,5S)-3-benzoyl-5-hydroxy-2,2-dimethylthiazolidine-4-carboxamido)oxy)acetate 
• 1334521-58-2 (4R,5S)-3-benzoyl-N-(benzyloxy)-5-hydroxy-2,2-dimethylthiazolidine-4-carboxamide 
• 1334521-38-8 (4R,5S)-3-benzoyl-5-hydroxy-N-methoxy-2,2-dimethylthiazolidine-4-carboxamide 

Relevant articles and documents

Memory of chirality in the electrochemical oxidation of thiazolidine-4-carboxylic acid derivatives

Memory of chirality in the electrochemical oxidation of thiazolidine-4-carboxylic acid derivatives was observed. The relatively larger size of sulphur atom than the oxygen atom for oxazolidine-4-carboxylic acid derivative may slightly improved the enantioselectivities of the oxidized products. The bulkier penicillamine derivative 1c furnished 2c with much better enantioselectivity (91% ee) than that of the cysteine derivative 2b (85% ee). The presence of two extra dimethyl groups, for the penicillamine derivative improved the enantioselectivities of the thiazolidine derivatives from 85% ee to 91 % ee.