57704-83-3

Upstream product

• 54736-49-1 1-bromoacenaphthylene 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 100-07-2 4-methoxy-benzoyl chloride 
• 208-96-8 acenaphthylene 

Downstream Products

• 138857-15-5 (6bS,7R,7aR)-6b-(4-Methoxy-phenyl)-7,7a-dihydro-6bH-cyclopropa[a]acenaphthylene-7-carboxylic acid ethyl ester 
• 138857-15-5 (6bS,7S,7aR)-6b-(4-Methoxy-phenyl)-7,7a-dihydro-6bH-cyclopropa[a]acenaphthylene-7-carboxylic acid ethyl ester 
• 138857-17-7 (6bS,7S,7aR)-6b-(4-Methoxy-phenyl)-7,7a-dihydro-6bH-cyclopropa[a]acenaphthylene-7-carbaldehyde 
• 138857-18-8 (6bR,9aS)-6b-(4-Methoxy-phenyl)-6b,9a-dihydro-7-oxa-cyclopenta[a]acenaphthylene 

Relevant academic research and scientific papers

Rhodium-catalyzed coupling reaction of aroyl chlorides with alkenes

Aroyl chlorides react with acyclic and cyclic alkenes in the presence of a rhodium catalyst to give Mizoroki-Heck type and cyclization products, respectively. A rhodium-ethylene complex, [{RhCl(C2H 4)2}2], showed excellent performance for these reactions. Notably, the reactions can be conducted effectively under base- and phosphane-free conditions.

Synthesis of anti- and syn-Diol Epoxides of trans-4,5-Dihydro-4,5-dihydroxybenzofluoranthene and trans-9,10-Dihydro-9,10-dihydroxybenzofluoranthene

The preparation of diastereomeric anti- and syn-epoxides of benzofluoranthene (BjF) 4,5- and 9,10-dihydrodiols is described.The anti-diol epoxides were prepared from the corresponding dihydrodiols by epoxidation with m-chloroperbenzoic acid.The isomeri