57705-21-2Relevant articles and documents
Copper-catalyzed oxidative synthesis of 2-oxo-acetamidines from one-pot three-component reaction of aryl methyl ketones, secondary amines and anilines
Dutta, Leema,Bhuyan, Pulak J.
, p. 5770 - 5778 (2018)
Some novel 2-oxo-acetamidines were synthesized via one-pot three-component reaction of acetophenones, secondary amines and anilines in presence of CuI as catalyst. The reaction involved in a oxidation process of C (sp3)–H bonds of acetophenones
A copper iodide-catalyzed coupling reaction of benzofuran-3(2H)-ones with amines: an approach to α-ketoamides
Chen, Rongxiang,Dai, Wei,Jia, Ruo-Ling,Li, Wenbo,Ma, Xueji,Sun, Aili,Wang, Kai-Kai,Wang, Zhan-Yong,Zhao, Wei
supporting information, p. 5294 - 5297 (2021/06/30)
A CuI-catalyzed coupling reaction of benzofuran-3(2H)-ones with amines has been well established for the direct synthesis of α-ketoamides. This process involves C-O bond cleavage and CO/C-N bond formation. Mechanism studies indicated that this α-ketoamide formation reaction may involve a free radical process.