57706-89-5

Usage

Uses

Used in Pesticide Industry:
(2E)-3,7-dimethylocta-2,6-dien-1-yl phenylcarbamate is used as an insecticide for controlling a wide range of insects, including mosquitoes, ticks, and fleas. Its strong activity against these insects makes it an effective tool in managing and preventing infestations.
Used in Insect Repellent Products:
(2E)-3,7-dimethylocta-2,6-dien-1-yl phenylcarbamate is used as an active ingredient in insect repellent products such as sprays, lotions, and creams. It provides protection against insect bites and the diseases transmitted by insects, offering a reliable means of defense against potential health threats.
Used in Personal Care Industry:
In the personal care industry, (2E)-3,7-dimethylocta-2,6-dien-1-yl phenylcarbamate is utilized for its safety and efficacy in human skin applications. It is considered relatively safe with minimal risk of toxicity or irritation when used as directed, making it a preferred choice for consumer products aimed at protecting against insect-borne illnesses.

Upstream product

• 106-24-1 Geraniol 
• 103-71-9 phenyl isocyanate 

Downstream Products

• 122313-79-5 (6S,2E)-6,7-dihydroxy-6,7-O-isopropylidene-3,7-dimethyl-2-octen-1-yl phenylcarbamate 
• 122313-80-8 (6R,2E)-6,7-epoxy-3,7-dimethyl-2-octen-1-yl phenylcarbamate 
• 61262-94-0 (6S)-5,6-dihydroxy-5,6-O-isopropylidene-6-methylheptan-2-one 
• 61262-97-3 (4'S,2E)-3-methyl-5-(2',2',5',5'-tetramethyl-1',3'-dioxolan-4'-yl)-2-penten-1-ol 
• 136937-07-0 (6R,2E)-6-Acetoxy-7-hydroxy-3,7-dimethyloct-2-en-1-yl N-Phenylcarbamate 
• 136937-06-9 (6S,2E)-6-Acetoxy-7-hydroxy-3,7-dimethyloct-2-en-1-yl N-Phenylcarbamate 
• 122313-83-1 (6R,2E)-6,7-dihydroxy-3,7-dimethyl-2-octen-1-yl phenylcarbamate 
• 122405-39-4 racemic (2E)-6,7-dihydroxy-3,7-dimethyl-2-octen-1-yl phenylcarbamate 
• 122313-77-3 (6S,2E)-6,7-dihydroxy-3,7-dimethyl-2-octen-1-yl phenylcarbamate 
• 185759-00-6 C₁₇H₂₃NO₃ 

Relevant academic research and scientific papers

Catalytic Olefin Hydroamidation Enabled by Proton-Coupled Electron Transfer

Here we report a ternary catalyst system for the intramolecular hydroamidation of unactivated olefins using simple N-aryl amide derivatives. Amide activation in these reactions occurs via concerted proton-coupled electron transfer (PCET) mediated by an excited state iridium complex and weak phosphate base to furnish a reactive amidyl radical that readily adds to pendant alkenes. A series of H-atom, electron, and proton transfer events with a thiophenol cocatalyst furnish the product and regenerate the active forms of the photocatalyst and base. Mechanistic studies indicate that the amide substrate can be selectively homolyzed via PCET in the presence of the thiophenol, despite a large difference in bond dissociation free energies between these functional groups.

Mild and high-yielding molybdenum(VI) dichloride dioxide-catalyzed formation of Mono-, Di-, Tri-, and tetracarbamates from alcohols and aromatic or aliphatic isocyanates

Both molybdenum(VI) dichloride dioxide (MoO2Cl2) and its dimethylformamide (DMF) complex catalyze the addition of alcohols to isocyanates giving carbamates. Most additions proceeded to completion at room temperature within 20 min using as little as 0.1 mol% of the catalyst when working on a 1-mmol scale or just 100 ppm working on a 20-mmol scale. Sterically encumbered substrates reacted to completion when 1 mol% of the catalyst was employed. Diols, triols, and tetraols reacted with monoisocyanates likewise, as did monofunctional alcohols and diisocyanates. These pairings furnished di-, tri-, tetra-, and dicarbamates, respectively. Reactants, which were poorly soluble in CH2Cl2 at room temperature required elevating the temperature and possibly choosing a higher-boiling solvent (ClCH 2CH2Cl, DMF) as well. Additions of diols to diisocyanates were feasible, too, giving polycarbamates as we presume. Copyright

Exceptionally active catalysts for the formation of carbamates from alcohols and isocyanates: Molybdenum(VI) dichloride dioxide and its DMF complex

Small amounts of MoO2Cl2 or MoO2Cl 2(DMF)2 catalyze carbamate formation from an alcohol and isocyanates: 0.1 mol% of the respective additive allow primary, secondary or tertiary alcohols to add to aliphatic or aromatic isocyanates of varied steric hindrance within 20 minutes at room temperature. Typically the corresponding carbamate resulted in 100% yield. Only particularly hindered substrates required 1.0 mol% of the catalyst while as little as 0.01% sufficed for the phenylcarbamoylation of menthol. Catalytic amounts of DMAP accelerate carbamate formation from certain alcohols and isocyanates, too. Georg Thieme Verlag Stuttgart · New York.

Practical synthesis of allylic silanes from allylic esters and carbamates by stereoselective copper-catalyzed allylic substitution reactions

The first copper-catalyzed allylic substitution reactions of allylic acetates and carbamates employing a bis(triorganosilyl)zinc reagent are reported. This novel procedure avoids the use of stoichiometric amounts of copper salts which are usually mandatory with this chemistry. Application of this methodology to standard model substrates substantiates a high diastereoselectivity for the double bond geometry (E:Z) as well as the relative configuration (syn:anti).

SYNTHESIS OF SPIRO ORTHO ESTERS, SPIRO ORTHO CARBONATES, AND INTERMEDIATES

Ortho esters and ortho carbonates can be produced by alkylating esters and carbonates with, for example, the hexafluorophosphate salt of a trialkyl oxonium ion. The spiro species are useful intermediates in the synthesis of complex organic molecules. Synt

Scavenge-ROMP-filter: a facile strategy for soluble scavenging via norbornenyl tagging of electrophilic Reagents.

[reaction: see text] A new "chemical tagging" method for homogeneous electrophilic scavenging is described. The method utilizes 5-norbornene-2-methanol to scavenge/tag a variety of electrophiles that are present in excess. Once tagging is complete, the crude reaction mixture is subjected to a rapid ROM polymerization event utilizing the second generation Grubbs catalyst. This process yields a polymer that can be precipitated with methanol or ether/hexane, leaving products in excellent yield and purity.