61262-94-0

Basic information

• Product Name: (5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE
• Synonyms: (5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE;(5S)-5,6-ISOPROPYLIDENEDIOXY-6-METHYL-HEPTAN-2-ONE;(5S)-5,6-Isopropylidenedioxy-6-methyl-heptan-2-one,99%;(5S)-5,6-Isopropylidenedioxy-6-methyl-heptan-2-one(5S)-5,6-Dihydro-5,6-dihydroxy-6-methylheptan-2-one acetonide
• CAS NO: 61262-94-0
• Molecular Formula: C11H20O3
• Molecular Weight: 200.27
• Mol File: 61262-94-0.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 93 °C (0.1 mmHg)
• Flash Point: 92.8°C
• Appearance: /
• Density: 1.0487 (rough estimate)
• Vapor Pressure: 0.0284mmHg at 25°C
• Refractive Index: 1.4325-1.4345
• CAS DataBase Reference: (5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE(CAS DataBase Reference)
• NIST Chemistry Reference: (5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE(61262-94-0)
• EPA Substance Registry System: (5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE(61262-94-0)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 61262-94-0(Hazardous Substances Data)

Usage

Chemical Properties

clear colorless to yellow liquid

InChI:InChI=1/C11H20O3/c1-8(12)6-7-9-10(2,3)14-11(4,5)13-9/h9H,6-7H2,1-5H3/t9-/m0/s1

Upstream product

• 122313-77-3 (6S,2E)-6,7-dihydroxy-3,7-dimethyl-2-octen-1-yl phenylcarbamate 
• 57706-89-5 (E)-3,7-dimethylocta-2,6-dien-1-yl phenylcarbamate 
• 154004-86-1 5-[(E)-5-((S)-3,3-Dimethyl-oxiranyl)-3-methyl-pent-2-enyloxy]-benzo[1,3]dioxole 
• 153908-84-0 (E)-(S)-8-(Benzo[1,3]dioxol-5-yloxy)-2,6-dimethyl-oct-6-ene-2,3-diol 
• 21213-67-2 benzodioxole 6,7-epoxygeraniol 
• 27927-80-6 4-(3,7-dimethyl-1-octa-2,6-dienyloxy)-1,2-(methylenedioxy)benzene 
• 6138-90-5 trans-geranyl bromide 
• 153908-85-1 5-[(E)-3-Methyl-5-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-pent-2-enyloxy]-benzo[1,3]dioxole 
• 122313-79-5 (6S,2E)-6,7-dihydroxy-6,7-O-isopropylidene-3,7-dimethyl-2-octen-1-yl phenylcarbamate 

Downstream Products

• 61262-97-3 (4'S,2E)-3-methyl-5-(2',2',5',5'-tetramethyl-1',3'-dioxolan-4'-yl)-2-penten-1-ol 

Relevant articles and documents

Microbiological transformation. 30. Enantioselective hydrolysis of racemic epoxides: The synthesis of enantiopure insect juvenile hormone analogs (Bower's compound)

The enantioselective epoxide biohydrolysis of the racemic benzodioxole 6,7-epoxygeraniol derivative 1 has been achieved using the fungus A. niger. This new type of preparative scale bioconversion allows the synthesis of both enantiomers of Bower's compound, an analogue of insect juvenile hormone. Biological tests showed that the 6(R) enantiomer was about ten times more active than the 6(S) enantiomer against the yellow meal worm Tenebrio molitor.

Synthesis of (-)-(R)-nephthenol and (-)-(R)-cembren A

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