57766-97-9

Upstream product

• 67-56-1 methanol 
• 1515-78-2 buta-1,3-dien-1-ylbenzene 
• 17488-65-2 4-phenylbut-3-en-2-ol 
• 74-88-4 methyl iodide 
• 154503-15-8 ((E)-3-Isopropoxy-but-1-enyl)-benzene 

Downstream Products

• 101266-90-4 ((E)-3-Propoxy-but-1-enyl)-benzene 
• 154503-15-8 ((E)-3-Isopropoxy-but-1-enyl)-benzene 
• 67685-90-9 methyl 3-phenyl-1-methylpropyl ether 
• 1309466-63-4 C₁₄H₂₁O₃PS 
• 169694-34-2 (3-methyl-1,5-hexadien-1-yl)-benzene 
• 73222-65-8 1-methyl-3-phenylhexa-1,5-diene 
• 74608-23-4 4-methyl-N-(4-phenylbut-3-en-2-yl)benzenesulfonamide 
• 122-57-6 1-Phenylbut-1-en-3-one 

Relevant academic research and scientific papers

Stereoselective synthesis of allyl ethers using α,β-unsaturated acylsilanes

The reaction behavior of silylvinylmethanols with acid catalysts was investigated. The starting silylvinylmethanols 2 were prepared by the reaction of the corresponding α,β-unsaturated acylsilanes 1 with organocerium reagents. The reaction of 2 with TsOH

Iron-catalyzed N-alkylation using π-activated ethers as electrophiles

A new method for the synthesis of diverse N-alkylation compounds was developed via an iron-catalyzed etheric Csp3-O cleavage with the C-N bond formation in the reaction of π-activated ethers with various nitrogen-based nucleophiles. In addition, the mechanism of this reaction was investigated. The Royal Society of Chemistry 2013.

Indium(i)-catalyzed alkyl-allyl coupling between ethers and an allylborane

An efficient method for alkyl-allyl cross-coupling between ethers and a 9-BBN-derived allylborane catalyzed by indium(i) triflate has been developed. The allylborane proved to be essential to obtain the desired products in high yields. The reaction displayed good substrate scope including high functional group tolerance. The Royal Society of Chemistry 2011.

Transetherification of allylic and benzylic ethers in the presence of ferric ion

Alcoholysis of allylic, secondary and tertiary benzylic ethers is proceeded efficiently in the presence of catalytic amounts of ferric ion as anhydrous FeCl3 and Fe(ClO4)3.

Selective and efficient alcoholyses of allylic, secondary- and tertiary benzylic alcohols in the presence of iron(III)

An efficient and selective method for the conversion of allylic, secondary- and tertiary benzylic alcohols into their corresponding ethers in the presence of iron(III) as FeCl3 and Fe(ClO4)3 under solvolytic condition is d

Cerium(IV), as a selective and efficient catalyst for alcoholyses of allylic and tertiary benzylic alcohols

An efficient and selective method is described for the catalytic conversion of allylic, and tertiary benzylic alcohols into their corresponding ethers in the presence of Ce(IV) under solvolytic and non- solvolytic conditions.

Photochemistry of Arylbutadienes. Part 2. Preparation and Photochemistry of 1-(Substituted-aryl)butadienes. A Ground-state Substituent Effect on an Excited-state Reaction

Yields and quantum yields are reported for the photoaddition of methanol to 1-phenylbutadiene and eight substituted 1-phenylbutadienes.For allyl and homoallyl products log Φ correlates more satisfactorily with ground-state substituent constants than with excited-state constants; for cyclopropylmethyl products, no correlation is observed with either set of constants.

Photochemistry of Arylbutadienes. Part 3. Mechanisms of Photoaddition of Methanol to 1-Arylbutadienes

The mechanism of formation of methyl ethers from irradiation of 1-arylbutadienes in methanol has been studied by deuterium labelling, fluorescence quenching, sensitisation, and kinetic studies.Cyclopropylmethyl ethers arise by a bicyclobutane mechanism; allyl and homoallyl ethers are formed by reaction of methanol with the 1Bu-like excited singlet diene to produce carbocation intermediates.