57768-34-0Relevant academic research and scientific papers
Diastereoselective Sulfenylation Reactions Employing N-(Phenylthio)lactams under Nonbasic Conditions
Wilson, Lawrence J.,Liotta, Dennis C.
, p. 1948 - 1950 (2007/10/02)
Silyl enol ethers and silyl ketene acetals react with sulfenamides in the presence of trimethylsilyl triflate to give the corresponding trans-sulfenylated ketones and lactones.
New Mild Methodology for the Synthesis of α-Phenylthio and α-Phenylseleno Ketones
Magnus, Philip,Rigollier, Pascal
, p. 6111 - 6114 (2007/10/02)
Treatment of trimethylsilyl enol ethers with the adduct 1, derived from chloramine-T and (PhS)2, gave good yields of α-phenylthioketones.The selenium version of this reagent 2 gave α-phenylselenoketones.
Thiosulfonic S-Esters; 6. Fluoride-Mediated α-Phenylsulfenylation of Cyclic Ketones and Esters via their Trimethylsilyl Enol Ethers
Caputo, Romualdo,Ferreri, Carla,Palumbo, Giovanni
, p. 464 - 466 (2007/10/02)
Ketones and carboxylic acid esters are conveniently converted to their α-sulfenylated derivatives.This new procedure is likely to represent the first reliable one for regiospecific monosulfenylation of carbonyl compounds.It is based on the reaction of the
CARBENOID TYPE BASE INDUCED RING EXPANSION OF THE ADDUCTS OF CYCLIC KETONES WITH BIS(PHENYLTHIO)METHYLLITHIUM
Abraham, William D.,Bhupathy, M.,Cohen, Theodore
, p. 2203 - 2206 (2007/10/02)
In another application of the principle that metallo derivatives of bis(phenylthio)acetals behave as carbenoids when present in the same molecule with another anionic group, the adducts of cyclic ketones with bis(phenylthio)methyllithium react with an alk
REGIOSPECIFIC SYNTHESIS OF α-(PHENYLTHIO)KETONES VIA RHODIUM(II) ACETATE CATALYSED ADDITION OF THIOPHENOL TO α-DIAZOKETONES
McKervey, M. Anthony,Ratananukul, Piniti
, p. 2509 - 2512 (2007/10/02)
αα-Addition of thiophenol to α-diazoketones is catalysed efficiently by rhodium(II) acetate in benzene solution at room temperature, offering a convenient regiospecific route to a variety of α-(phenylthio)ketones.
