28833-59-2

Upstream product

• 127-65-1 chloroamine-T 
• 882-33-7 diphenyldisulfane 

Downstream Products

• 110452-14-7 2-phenylthiocyclohexanone 
• 54376-46-4 2-methyl-2-(phenylthio)cyclohexan-1-one 
• 57768-34-0 2-(phenylthio)-6-methylcyclohexanone 
• 52190-42-8 2-phenylsulfanylcyclooctanone 
• 52190-41-7 2-phenylsulfanylcycloheptanone 
• 52190-43-9 2-(phenylthio)cyclododecan-1-one 
• 107288-42-6 7-(phenylthio)-1,4-dioxaspiro[4.5]decan-8-one 
• 104281-51-8 2-(phenylthio)cyclododecanone 
• 144810-05-9 Triisopropyl-(2-phenylsulfanyl-cyclohex-1-enyloxy)-silane 
• 144810-06-0 Triisopropyl-(6-phenylsulfanyl-cyclohex-1-enyloxy)-silane 
• 52190-40-6 2-(phenylthio)cyclopentanone 
• 68820-03-1 N-[(3S,5S,8R,9S,10S,13R,14S,17R)-17-((R)-1,5-Dimethyl-hexyl)-10,13-dimethyl-3-phenylsulfanyl-hexadecahydro-cyclopenta[a]phenanthren-(2Z)-ylidene]-4-methyl-benzenesulfonamide 
• 68820-06-4 5-(p-Tolylsulfonylamino)-4-phenylthiopentan-1-ol 
• 68922-82-7 N,N'-bis-(toluene-4-sulfonyl)-benzolsulfynamidine; sodium-salt 

Relevant academic research and scientific papers

Comparison of the reactivity of N-(p-toluenesulfonyl)-sulfinimidoyl fluorides and chlorides toward triphenylphosphine

The path of the reaction of aryl-N-(p-toluenesulfonyl)-sulfinimidoyl fluorides and triphenylphosphine is highly dependent on the order of the reactants addition. Addition of triphenylphosphine to aryl-N-(p-toluenesulfonyl) -sulfinimidoyl fluorides results in the formation of triphenyl(arylthio) phosphonium salts of N,N′-bis(p-toluenesulfonyl)aryl-sulfinamidines and triphenyldifluorophosphorane. By changing the reagent addition order, we obtained triphenyldifluorophosphorane, P, P, P-triphenyl- N- (p-toluenesulfonyl)-phosphine imide, and diaryl disulfides. The outcome of the reaction aryl-N-(arenesulfonyl)-sulfinimidoyl chlorides and triphenylphosphine does not depend on the order of addition of the reactants. P,P,P-Triphenyl-N- (arenesulfonyl)-phosphine imides, triphenyldichlorophosphorane, and diaryl disulfides were formed as a result.