57772-72-2Relevant articles and documents
Catalyzation of 1,4-additions of arylboronic acids to α,β- unsaturated substrates using nickel(I) complexes
Meng, Jing-Jing,Gao, Min,Dong, Min,Wei, Yu-Ping,Zhang, Wen-Qin
, p. 2107 - 2109 (2014/04/03)
Nickel(I) complexes were generated in situ from Ni (PPh3) 2Cl2 using activated iron and the complexes combined with N,N′-bis(4-fluorobenzylidene) ethane-1,2-diamine (BFBED) were then used as a catalyst for the 1,4-addition reaction of arylboronic acids to α,β-unsaturated substrates. The reaction proceeded to completion and did not require the addition of a base but the addition of potassium iodide is crucial to this cross-coupling reaction. Moreover, experimental observations suggested a possible Ni(I)-Ni(III) catalytic cycle mechanism.
SYNTHESIS AND PROPERTIES OF SOME N,N,-DIALKYLAMIDES AS NEW EXTRACTANTS.
Al-Jallo,Hussain,Mansoor,Sameh,Al-Saidi
, p. 479 - 481 (2007/10/02)
Forty-seven new N,N-dialkylamides were prepared and their physical and spectral data are tabulated. The solubility of amides 1-47 in organic and aqueous solvents was tested and the results showed that as the amides are freely soluble in organic solvents t
