577973-96-7

Basic information

• Product Name: Acetic acid, bromo[[(phenylmethoxy)carbonyl]amino]-, ethyl ester
• CAS NO: 577973-96-7
• Molecular Formula: C12H14BrNO4
• Molecular Weight: 316.14800
• Mol File: 577973-96-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetic acid, bromo[[(phenylmethoxy)carbonyl]amino]-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, bromo[[(phenylmethoxy)carbonyl]amino]-, ethyl ester(577973-96-7)
• EPA Substance Registry System: Acetic acid, bromo[[(phenylmethoxy)carbonyl]amino]-, ethyl ester(577973-96-7)

Safety Data

• Hazardous Substances Data: 577973-96-7(Hazardous Substances Data)

Upstream product

• 83026-98-6 N-carbobenzoxy-α-ethoxyglycine ethyl ester 

Downstream Products

• 81357-12-2 [(E)-Benzyloxycarbonylimino]-acetic acid ethyl ester 

Relevant articles and documents

Catalytic, asymmetric Mannich-type reactions of α-imino esters bearing readily removable substituents on nitrogen

(Matrix presented) Catalytic, enantioselective Mannich-type reactions of α-imino esters bearing readily removable substituents on nitrogen are described. Several N-carbamate-protected α-imino esters, which are readily prepared from 2-bromoglycine esters using a polymer-supported amine, reacted with silicon enolates to afford the desired adducts in high yields with high enantioselectivity using a copper(II)-diamine complex. Easy deprotection of the product amine and transformation to free o-amino acid derivatives have also been demonstrated.