578007-60-0Relevant articles and documents
A concise and practical synthesis of antigenic globotriose, α-d-Gal-(1→4)-β-d-Gal-(1→4)-β-d-Glc
Chen, Langqiu,Zhao, Xing-E.,Lai, Duan,Song, Zhiwei,Kong, Fanzuo
, p. 1174 - 1180 (2007/10/03)
A concise and practical synthesis of the antigenic globotriose, α-d-Gal-(1→4)-β-d-Gal-(1→4)-β-d-Glc (13), was achieved by coupling of a monosaccharide donor, 3-O-allyl-2-O-benzoyl-4,6-O-benzylidene-α-d-galactopyranosyl trichloroacetimidate (4) with a disa
'Armed-disarmed' glycosidation strategy based on glycosyl donors and acceptors carrying phosphoroamidate as a leaving group: A convergent synthesis of globotriaosylceramide
Hashimoto, Shun-Ichi,Sakamoto, Hiroki,Honda, Takeshi,Abe, Hiroshi,Nakamura, Sei-Ichi,Ikegami, Shiro
, p. 8969 - 8972 (2007/10/03)
A stereocontrolled synthesis of globotriaosylceramide with three different glycosidic linkages has been accomplished by linear and convergent routes exploiting 'armed-disarmed' glycosidation methodology based on glycosyl donors and acceptors carrying tetramethylphosphoroamidate as a leaving group. In particular, the convergent strategy featuring a coupling of a galactosyl(1→4)-galactosyl donor with a glucosylceramide derivative has proven to be extremely efficient.