57826-17-2Relevant academic research and scientific papers
Efficient highly selective synthesis of methyl 2-(ethynyl)alk-2(E)-enoates and 2-(1′-chlorovinyl)alk-2(Z)-enoates from 2-(methoxycarbonyl)-2,3- allenols
Deng, Youqian,Jin, Xin,Fu, Chunling,Ma, Shengming
supporting information; experimental part, p. 2169 - 2172 (2009/09/28)
Highly regio- and stereoselective reactions of readily available 2-(methoxycarbonyl)-2,3-allenols 1 with oxalyl chloride in the presence of Et3N or DMSO afforded methyl 2-(ethynyl)alk-2(E)-enoates(E)-2 and 2-(1′-chlorovinyl)alk-2(Z)-enoates(Z)-
