578729-63-2Relevant academic research and scientific papers
Synthesis of α- and β-C-glycosides of N-acetylglucosamine
McGarvey, Glenn J.,Schmidtmann, Frank W.,Benedum, Tyler E.,Kizer, Darin E.
, p. 3775 - 3779 (2003)
As part of efforts to make available new classes of bioactive C-glycoconjugates, D-glucosamine has been effectively converted into a series of 2-deoxy-2-amino-C-glycosides. This versatile approach is keyed by a remarkably effective metal catalyzed olefin isomerization of the isomeric C-allyl amino sugars which, in turn, are readily available via radical allylation of D-glucosamine.
