652993-94-7Relevant academic research and scientific papers
A short synthetic route to β-C-glycosides of N-acetylglucosamine
Rat, Stéphanie,Norsikian, Stéphanie
, p. 1004 - 1008 (2006)
A short and efficient process is described for the synthesis of protected and unprotected 1-formyl-C-glycosides of N-acetylglucosamine. Georg Thieme Verlag Stuttgart.
New and general synthesis of β-C-glycosylformaldehydes from easily available β-C-glycosylpropanones
Norsikian, Stephanie,Zeitouni, Jennifer,Rat, Stephanie,Gerard, Sylvie,Lubineau, Andre
, p. 2716 - 2728 (2008/03/14)
A highly effective method for the introduction of a formyl group at the anomeric position of pyranosides was developed via enolisation of β-C-d-glycopyranosylpropan-2-one using thermodynamic conditions then oxidative cleavage of the more substituted doubl
Synthesis of α- and β-C-glycosides of N-acetylglucosamine
McGarvey, Glenn J.,Schmidtmann, Frank W.,Benedum, Tyler E.,Kizer, Darin E.
, p. 3775 - 3779 (2007/10/03)
As part of efforts to make available new classes of bioactive C-glycoconjugates, D-glucosamine has been effectively converted into a series of 2-deoxy-2-amino-C-glycosides. This versatile approach is keyed by a remarkably effective metal catalyzed olefin isomerization of the isomeric C-allyl amino sugars which, in turn, are readily available via radical allylation of D-glucosamine.
Synthesis of C-Glycosyl Phosphate and Phosphonate, Analogues of N-Acetyl-α-D-Glucosamine 1-Phosphate
Gaurat, Olivier,Xie, Juan,Valery, Jean-Marc
, p. 645 - 656 (2007/10/03)
Synthesis of α-C-ethylene phosphate and phosphonate as well as α-C-methylene phosphate analogues of N-acetyl-α-D-glucosamine 1-phosphate is reported starting from the common perbenzylated 2-acetamido-2-deoxy-α-C-allyl glucoside. Anomerisation of the corre
