57892-29-2Relevant academic research and scientific papers
Synthesis and properties of carbamoyl derivatives of photolabile benzoins
Papageorgiou, George,Corrie, John E.T.
, p. 3917 - 3932 (2007/10/03)
Carbamoyl derivatives of photolabile benzoins, particularly of 3',5'-dimethoxybenzoin, are readily prepared via the mixed p-nitrophenyl carbonate of the benzoin. The method is most suitable for secondary amines, since many primary amines exist in varying proportions as the cyclic In alkaline solution (0.2 M NaOH) the carbamates of unsymmetrical benzoins are readily equilibrated. Flash photolysis of 3',5'-dimethoxybenzoin carbamates generates the carbamate anion in a fast heterolytic process and liberation of the amine is controlled by the rate of decarboxylation.
Skeletal Rearrangement of N,O-Heterocycles. The Isoxazolinone to Aziridine Transformation Induced by Lithium Aluminium Hydride
Chidichimo, G.,Cum, G.,Lelj, F.,Sindona, G.,Uccella, N.
, p. 1372 - 1377 (2007/10/02)
Triphenylisoxazolinone reacts with lithium aluminium hydride to yield either triphenylaziridinic derivatives or open-ring products or both depending on reaction conditions.The structures of the products were ascertained by spectroscopic methodes and their
