73652-65-0Relevant academic research and scientific papers
Expedient stereospecific Co-catalyzed tandem C-N and C-O bond formation of: N -methylanilines with styrene oxides
Satheesh, Vanaparthi,Vivek Kumar, Sundaravel,Punniyamurthy, Tharmalingam
, p. 11813 - 11816 (2018/12/01)
Cobalt(ii)-catalyzed stereospecific coupling of N-methylanilines with styrene oxides is developed via tandem C-N and C-O bond formation using tert-butyl hydroperoxide (TBHP) as an oxidant. Optically active epoxide can be reacted with high optical purity.
Sn(OTf)2 catalysed regioselective styrene oxide ring opening with aromatic amines
Mancilla, Gabriela,Femenía-Ríos, Marienca,Macías-Sánchez, Antonio J.,Collado, Isidro G.
experimental part, p. 11732 - 11737 (2009/04/11)
Sn(OTf)2 is an efficient and versatile catalyst for the highly regioselective opening of styrene oxide with aromatic amines, which allowed for the preparation of fourteen 2-arylamino-2-phenylethanols, some of them described here for the first time (6g, 6i, 6j, 6k and 6m). Sn(OTf)2 also catalyses the opening of styrene oxide with aliphatic amines in moderate to high yields but with a lower degree of regioselectivity. 2-Akylamino-1-phenylethanols are the predominant products when moderate to high regioselectivity is observed (compounds 4b, 4c and 4d). This is the first report of the use of Sn(OTf)2 to catalyse the opening of an epoxide by aliphatic amines.
Skeletal Rearrangement of N,O-Heterocycles. The Isoxazolinone to Aziridine Transformation Induced by Lithium Aluminium Hydride
Chidichimo, G.,Cum, G.,Lelj, F.,Sindona, G.,Uccella, N.
, p. 1372 - 1377 (2007/10/02)
Triphenylisoxazolinone reacts with lithium aluminium hydride to yield either triphenylaziridinic derivatives or open-ring products or both depending on reaction conditions.The structures of the products were ascertained by spectroscopic methodes and their
