579488-71-4Relevant academic research and scientific papers
One-pot rhodium(I)-catalyzed hydroboration of alkenes: Radical conjugate addition
Renaud, Philippe,Ollivier, Cyril,Weber, Valery
, p. 5769 - 5772 (2007/10/03)
B-Alkylcatecholboranes, prepared by rhodium-(I)-catalyzed hydroboration of alkenes, are suitable radical precursors for conjugate addition to activated olefins. This procedure proved to be particularly useful for the control of the regio- and chemoselectivity of such tandem processes. Enantioselective hydroboration has also been successfully coupled with radical chain reaction in a one-pot process.
