579488-92-9Relevant academic research and scientific papers
Structural incongruities of coleophomone natural products: Insights by total synthesis of a semi-synthetic derivative
Bode, Jeffrey W.,Suzuki, Keisuke
, p. 3559 - 3563 (2007/10/03)
An unexpected structural incongruity between coleophomones 1 and the reported structure of recently isolated natural product 2 was confirmed by total synthesis of key semi-synthetic derivative 3 and its positional isomer 4. In addition, possible mechanism
Amine-promoted cyclocondensation of highly substituted aromatic nitrile oxides with diketones
Bode, Jeffrey W.,Hachisu, Yoshifumi,Matsuura, Tomoo,Suzuki, Keisuke
, p. 3555 - 3558 (2007/10/03)
Base-promoted cyclocondensation of hindered nitrile oxides and cyclic diketones affords highly functionalized, sterically-encumbered isoxazole products in good yield. The mild reaction conditions (NEt3, EtOH) are tolerant to a wide variety of f
