57959-48-5

Upstream product

• 79314-63-9 ethyl 2,2-dimethyl-3-hydroxypent-4-enoate 
• 100-52-7 benzaldehyde 

Downstream Products

• 60533-05-3 3-(6-methoxy-[2]naphthyl)-2,2-dimethyl-pent-3-enoic acid 
• 494790-07-7 ethyl 3-oxo-10-phenyl-2,2,4-trimethyldeca-(4E,6E,8E)-trienoate 
• 666739-66-8 C₂₀H₃₀O₅ 

Relevant academic research and scientific papers

Development of new iron catalysts for the tandem isomerization-aldol condensation of allylic alcohols

(bda)Fe(CO)3 and (COT)Fe(CO)3 are shown to be excellent catalysts for the tandem isomerization-aldol reaction of allylic alcohols with aldehydes and to significantly increase the scope of this aldolization process, especially, in the

From allylic alcohols to aldols via a novel, tandem isomerization-condensation catalyzed by Fe(CO)5

Allylic alcohols react with aldehydes, in the presence of catalytic amounts of Fe(CO)5 and under irradiation, to give mainly aldol products. A small amount of ketone resulting from the classical isomerization process is also isolated. This new aldol-type reaction is a complete atom economy process occurring under neutral conditions.