581083-15-0Relevant articles and documents
Preparation of 2,3-Disubstituted 5-Bromo-1 H -pyrrolo[2,3- b ]pyridine Framework by Fischer Cyclization
Alekseyev, Roman S.,Amirova, Sabina R.,Terenin, Vladimir I.
, p. 3169 - 3178 (2015/10/19)
A simple synthesis of some hard-to-reach heterocycles containing 2,3-disubstituted 5-bromo-1H-pyrrolo[2,3-b]pyridine framework by FisNher indole cyclization in polyphosphoric acid has been developed. A particularly valuable feature of this synthetic route is the possibility to build a 5-bromo-7-azaindole scaffold with alkyl or aryl substituents at positions 2 and 3 from available starting materials.
Efficient synthesis of bromocyclopenta[b]indoles via a bromination - Reduction sequence
Lachance, Nicolas,Chan, Wing Yan
, p. 289 - 295 (2007/10/03)
Substituted cyclopenta[b]indoles are selectively brominated in good yields with excess pyridine - Br2 charge-transfer complex (PyBr2) in a one-pot reaction to provide 5 and/or 7-bromoindoles. The mechanism involves the formation of a
