58139-07-4Relevant articles and documents
Evidence of enhanced conjugation in ortho -arylene ethynylenes with transition metal coordination
Ren, Qianwei,Reedy, Cole G.,Terrell, Eric A.,Wieting, Joshua M.,Wagie, Robert W.,Asplin, Jake P.,Doyle, Leah M.,Long, Steven J.,Everard, Michael T.,Sauer, Jon S.,Baumgart, Cassandra E.,D'Acchioli, Jason S.,Bowling, Nathan P.
experimental part, p. 2571 - 2577 (2012/05/05)
The effective conjugation of ortho and ortho-alt-para-arylene ethynylenes, with appropriately positioned pyridine and pyrazine heterocycles, increases upon binding to Ag(I) and Pd(II) cations. Significant bathochromic shifts in the electronic spectra, wit
First metallation of iodo diazines. Iodo and nitrogen directed metallations. Diazines XXII
Ple, Nelly,Turck, Alain,Heynderickx, Arnault,Queguiner, Guy
, p. 9701 - 9710 (2007/10/03)
Lithiation of iodopyrazine and 4-iodo-2-methylthiopyrimidine followed by reaction with various electrophiles was successfully achieved and was used to synthesize new pyrazine and pyrimidine derivatives. Iodo and nitrogen directed metallations were observed.