58165-83-6Relevant academic research and scientific papers
Comparative study of the photochemistry of the azidopyridine 1-oxides
Crabtree, Kyle N.,Hostetler, Katherine J.,Munsch, Tamara E.,Neuhaus, Patrik,Lahti, Paul M.,Sander, Wolfram,Poole, James S.
, p. 3441 - 3451 (2008/09/20)
(Chemical Equation Presented) The photochemistry of azidopyridine 1-oxides was studied using an array of glass and matrix isolation techniques. As with room temperature, the photochemistry of 4-azidopyridine 1-oxide is dominated by triplet nitrene chemistry. However, in the case of the 3-azide, matrix photolysis indicates the formation of diazabicyclo[4.1.0]hepta-2,4,6-triene N-oxide and diazacycloheptatetraene N-oxide intermediates as well as triplet nitrene.
REDUCTION OF AROMATIC NITRO GROUPS WITH HEXAMETHYLDISILANE1): REACTIONS WITH HEXAMETHYLDISILANE AND FLUORIDE ION-II2).
Vorbrueggen, Helmut,Krolikiewicz, Konrad
, p. 1259 - 1262 (2007/10/02)
Reduction of aromatic nitro compounds with hexamethyldisilane and fluoride ion in THF at 24 deg C gives the corresponding azo- and azoxy-compounds in high yields.Hexamethyldisilane converts commercial tetrabutylammoniumfluoride-dihydrate into a highly reactive catalyst.
