58173-92-5Relevant articles and documents
Carbon-carbon bond forming reactions by using bistrifluoromethanesulfonimide
Cossy,Lutz,Alauze,Meyer
, p. 45 - 48 (2007/10/03)
Bistrifluoromethanesulfonimide has been used to catalyze C-C bond forming reactions such as Friedel-Crafts, Mukaiyama, 1,2-addition and 1,4-addition as well as C-glycosidation reactions.
TRIMETHYLSILYLDIAZOMETHANE: A CONVENIENT REAGENT FOR THE O-METHYLATION OF ALCOHOLS
Aoyama, Toyohiko,Shioiri, Takayuki
, p. 5507 - 5508 (2007/10/02)
Trimethylsilyldiazomethane smoothly reacts with alcohols in dichloromethane in the presence of 42percent aqueous fluoroboric acid to give methyl ethers in good to high yields.
TRIMETHYLSILYL TRIFLATE CATALYZED ALDOL-TYPE REACTION OF ENOL SILYL ETHERS AND ACETALS OR RELATED COMPOUNDS
Murata, Shizuaki,Suzuki, Chikusa,Noyori, Ryoji
, p. 4259 - 4276 (2007/10/02)
Trimethylsilyl triflate with or without added hindered tertiary amines catalyzes directed condensation of enol trimethylsilyl ethers with acetals, orthoformate, or 2-acetoxytetrahydrofuran or -pyrans to give the corresponding β-alkoxy carbonyl compounds.R
TRIMETHYLSILYL TRIFLATE IN ORGANIC SYNTHESIS
Noyori, R.,Murata, S.,Suzuki, M.
, p. 3899 - 3910 (2007/10/02)
Trimethylsilyl triflate is a powerful silylating agent for organic compounds and acts as a catalyst which accelerates a variety of nucleophilic reactions in aprotic media.The reactions proceed via one-center, electrophilic coordination of the silyl group to hetero functional groups and exhibit unique selectivities.
CONDENSATION OF ENOL SILYL ETHERS AND DIALKOXYMETHANES CATALYZED BY TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE. REGIOSPECIFIC SYNTHESIS OF α-ALKOXYMETHYL KETONES
Murata, S.,Suzuki, M.,Noyori, R.
, p. 2527 - 2528 (2007/10/02)
A facile, regiospecific entry to α-alkoxymethyl ketones is described.
